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144026-79-9,MFCD00798539
Catalog No.:AA001IR8

144026-79-9 | Scandium(iii) trifluoromethanesulfonate

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  • Technical Information
  • Properties
  • Literature
Technical Information
Catalog Number:
AA001IR8
Chemical Name:
Scandium(iii) trifluoromethanesulfonate
CAS Number:
144026-79-9
Molecular Formula:
C3F9O9S3Sc
Molecular Weight:
492.1632
MDL Number:
MFCD00798539
SMILES:
FC(S(=O)(=O)[O-])(F)F.FC(S(=O)(=O)[O-])(F)F.FC(S(=O)(=O)[O-])(F)F.[Sc+3]
Properties
Properties
 
Form:
Solid  
MP:
300 °C  
Stability:
Hygroscopic  
Storage:
Inert atmosphere;Room Temperature;  

Computed Properties
 
Complexity:
145  
Covalently-Bonded Unit Count:
4  
Heavy Atom Count:
25  
Hydrogen Bond Acceptor Count:
18  

Literature

Title: Lewis acid trapping of an elusive copper-tosylnitrene intermediate using scandium triflate.

Journal: Journal of the American Chemical Society 20120912

Title: Catalytic asymmetric sulfenylation of unprotected 3-substituted oxindoles.

Journal: Organic letters 20120601

Title: Sc(OTf)3-catalyzed synthesis of indoles and SnCl4-mediated regioselective hydrochlorination of 5-(arylamino)pent-3-yn-2-ones.

Journal: The Journal of organic chemistry 20111021

Title: Chiral Sc-catalyzed asymmetric Michael reactions of thiols with enones in water.

Journal: Organic & biomolecular chemistry 20110521

Title: Efficient conversion of triacylglycerols and fatty acids to biodiesel in a microwave reactor using metal triflate catalysts.

Journal: Organic & biomolecular chemistry 20101021

Title: Highly enantioselective synthesis of alpha-stereogenic esters through catalytic asymmetric michael addition of 4-oxo-4-arylbutenoates.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20100903

Title: Scandium triflate-catalyzed one-pot domino approach towards general and efficient syntheses of unsymmetrical 9-substituted xanthene derivatives.

Journal: Organic & biomolecular chemistry 20100307

Title: Selective heteronuclear Hartmann-Hahn: a multiple-pulse sequence for selective magnetization transfer in the structural elucidation of 'isotagged' oligosaccharides.

Journal: Journal of magnetic resonance (San Diego, Calif. : 1997) 20100301

Title: Biomimetic synthesis of a new class of bacterial signaling molecules.

Journal: Organic letters 20090716

Title: Sc(OTf)(3)-catalyzed condensation of 2-alkyl-N-tosylaziridine with aldehydes or ketones: an efficient synthesis of 5-alkyl-1,3-oxazolidines.

Journal: Chemical communications (Cambridge, England) 20090714

Title: Alpha-sulfanyl and alpha-selanyl propadienyl cations: regioselective generations and cycloadditions with thioamides and selemides controlled by MeNO2-H2O system.

Journal: Organic letters 20090702

Title: Sc(OTf)3-catalyzed or t-BuOK promoted tandem reaction of 2-(2-(alkynyl)benzylidene)malonate with indole.

Journal: Organic letters 20080605

Title: Sc(OTf)3-mediated silylation of hydroxy functional groups on a solid surface: a catalytic grafting method operating at room temperature.

Journal: Angewandte Chemie (International ed. in English) 20080101

Title: Asymmetric Friedel-Crafts alkylation of indoles with methyl (E)-2-oxo-4-aryl-3-butenoates catalyzed by Sc(OTf)3/pybox.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20080101

Title: Enantioselective Friedel-Crafts alkylations catalyzed by bis(oxazolinyl)pyridine-scandium(III) triflate complexes.

Journal: Journal of the American Chemical Society 20070815

Title: Highly diastereoselective synthesis of beta-carboxy-gamma-lactams and their ethyl esters via Sc(OTf)(3)-catalyzed imino Mukaiyama-aldol type reaction of 2,5-bis(trimethylsilyloxy)furan with imines.

Journal: The Journal of organic chemistry 20070622

Title: First catalytic and green synthesis of aryl-(Z)-vinyl chlorides and its plausible addition-elimination mechanism.

Journal: Organic letters 20070315

Title: Mild reductive opening of aryl pyranosides promoted by scandium(III) triflate.

Journal: Journal of the American Chemical Society 20070110

Title: Direct C-glycosylation of indole with unprotected mono-, di-, and trisaccharides: a one-pot synthesis of 1-deoxy-1,1-bis(3-indolyl)alditols.

Journal: Carbohydrate research 20061127

Title: Catalytic enantioselective and diastereoselective addition of aldehyde-derived enecarbamates to alpha-oxo aldehydes.

Journal: Angewandte Chemie (International ed. in English) 20060602

Title: Scandium triflate catalyzed cycloaddition of imines with 1,1-cyclopropanediesters: efficient and diastereoselective synthesis of multi-substituted pyrrolidines.

Journal: Organic & biomolecular chemistry 20060121

Title: Catalytic asymmetric ring opening of meso-epoxides with aromatic amines in water.

Journal: Organic letters 20051013

Title: Enantioselective indole Friedel--Crafts alkylations catalyzed by bis(oxazolinyl)pyridine-scandium(III) triflate complexes.

Journal: Journal of the American Chemical Society 20030910

Title: Highly enantioselective 1,3-dipolar cycloaddition reactions of 2-benzopyrylium-4-olate catalyzed by chiral Lewis acids.

Journal: Journal of the American Chemical Society 20021218

Title: Scandium(III) trifluoromethanesulfonate catalyzed aromatic nitration with inorganic nitrates and acetic anhydride.

Journal: Chemical & pharmaceutical bulletin 20020801

Title: Direct formation of N-acylated amino acid derivatives via nucleophilic addition to N-acylimino esters using a polymer-supported amine and scandium triflate.

Journal: Journal of combinatorial chemistry 20010101

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