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251320-86-2,MFCD03094577
Catalog No.:AA002QI8

251320-86-2 | 2-(Dicyclohexylphosphino)-2'-methylbiphenyl

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250mg
97%
in stock  
$8.00   $6.00
- +
1g
97%
in stock  
$11.00   $8.00
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5g
97%
in stock  
$18.00   $13.00
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25g
95%
in stock  
$63.00   $45.00
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100g
97%
in stock  
$218.00   $153.00
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  • Technical Information
  • Properties
  • Upstream Synthesis Route
  • Downstream Synthesis Route
  • Literature
  • Request for Quotation
  • Download SDS
  • Technical Information
  • Properties
  • Upstream Synthesis Route
  • Downstream Synthesis Route
  • Literature
Technical Information
Catalog Number:
AA002QI8
Chemical Name:
2-(Dicyclohexylphosphino)-2'-methylbiphenyl
CAS Number:
251320-86-2
Molecular Formula:
C25H33P
Molecular Weight:
364.5033
MDL Number:
MFCD03094577
SMILES:
Cc1ccccc1c1ccccc1P(C1CCCCC1)C1CCCCC1
Properties
Computed Properties
 
Complexity:
388  
Covalently-Bonded Unit Count:
1  
Heavy Atom Count:
26  
Rotatable Bond Count:
4  
XLogP3:
7.1  

Upstream Synthesis Route

[1]JournaloftheAmericanChemicalSociety,1999,vol.121,#41,p.9550-9561

[1]AdvancedSynthesisandCatalysis,2001,vol.343,#8,p.789-794

[1]JournaloftheAmericanChemicalSociety,1999,vol.121,#41,p.9550-9561

[2]EuropeanJournalofOrganicChemistry,2012,#11,p.2127-2131

[1]EuropeanJournalofOrganicChemistry,2012,#11,p.2127-2131

[1]JournaloftheAmericanChemicalSociety,1999,vol.121,#41,p.9550-9561

Downstream Synthesis Route

[1]JournaloftheAmericanChemicalSociety,1999,vol.121,p.9550-9561

[1]JournalofOrganicChemistry,2000,vol.65,p.5334-5341

[1]AdvancedSynthesisandCatalysis,2001,vol.343,p.789-794

251320-86-2   
C25H32(2)HP 

[1]AngewandteChemie-InternationalEdition,2006,vol.45,p.925-928

[1]AdvancedSynthesisandCatalysis,2001,vol.343,p.789-794

Literature

Title: Double N-arylation of primary amines: carbazole synthesis from 2,2'-biphenyldiols.

Journal: The Journal of organic chemistry 20050121

Title: Insights into the origin of high activity and stability of catalysts derived from bulky, electron-rich monophosphinobiaryl ligands in the Pd-catalyzed C-N bond formation.

Journal: Journal of the American Chemical Society 20031119

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SDS
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