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564483-18-7,MFCD04117682
Catalog No.:AA0032SM

564483-18-7 | Dicyclohexyl[2-(2,4,6-triisopropylphenyl)phenyl]phosphane

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Purity
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Price(USD)
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250mg
97%
in stock  
$6.00   $4.00
- +
5g
98%
in stock  
$10.00   $7.00
- +
10g
98%
in stock  
$18.00   $12.00
- +
25g
98%
in stock  
$35.00   $24.00
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100g
98%
in stock  
$110.00   $77.00
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  • Technical Information
  • Properties
  • Upstream Synthesis Route
  • Downstream Synthesis Route
  • Literature
  • Request for Quotation
  • Download SDS
  • Technical Information
  • Properties
  • Upstream Synthesis Route
  • Downstream Synthesis Route
  • Literature
Technical Information
Catalog Number:
AA0032SM
Chemical Name:
Dicyclohexyl[2-(2,4,6-triisopropylphenyl)phenyl]phosphane
CAS Number:
564483-18-7
Molecular Formula:
C33H49P
Molecular Weight:
476.7159
MDL Number:
MFCD04117682
SMILES:
CC(c1cc(cc(c1c1ccccc1P(C1CCCCC1)C1CCCCC1)C(C)C)C(C)C)C
Properties
Properties
 
BP:
569.8°C at 760 mmHg  
Form:
Solid  
MP:
187-190 °C(lit.)  
Stability:
Air Sensitive  
Storage:
Inert atmosphere;Room Temperature;  

Computed Properties
 
Complexity:
545  
Covalently-Bonded Unit Count:
1  
Heavy Atom Count:
34  
Rotatable Bond Count:
7  
XLogP3:
10.1  

Upstream Synthesis Route

[1]Patent:CN105273006,2016,A,.Locationinpatent:Paragraph0069;0070

[1]Patent:CN105273006,2016,A,.Locationinpatent:Paragraph0059

[1]JournaloftheAmericanChemicalSociety,2003,vol.125,#22,p.6653-6655

[2]Chemistry-AEuropeanJournal,2011,vol.17,#39,p.10828-10831

[3]OrganicProcessResearchandDevelopment,2004,vol.8,#6,p.1065-1071

[1]Chemistry-AEuropeanJournal,2011,vol.17,#39,p.10828-10831

[1]JournaloftheAmericanChemicalSociety,2008,vol.130,#21,p.6686-6687

Downstream Synthesis Route
564483-18-7   
2'-dicyclohexylphosphanyl-2,6-diisopropyl-biphenyl-4-sulfonicacid 

[1]AngewandteChemie-InternationalEdition,2005,vol.44,p.6173-6177

564483-18-7   
dicyclohexyl(2',4',6'-triisopropylbiphenyl-2-yl)phosphineoxide 

[1]JournaloftheAmericanChemicalSociety,2007,vol.129,p.5096-5101

[2]AngewandteChemie-InternationalEdition,2017,vol.56,p.5272-5276    Angew.Chem.,2017,vol.129,p.5356-5360,5

[3]Chemistry-AEuropeanJournal,2019,vol.25,p.6980-6987

564483-18-7   
sodium2'‐(dicyclohexylphosphaneyl)‐2,6‐diisopropyl‐1,1'‐biphenyl‐4‐sulfonate 

[1]Patent:US2006/173186,2006,A1.Locationinpatent:Page/Pagecolumn27;Sheet1

[2]JournaloftheAmericanChemicalSociety,2018,vol.140,p.13570-13574

120-72-9   
potassiumphosphate 
  890315-75-0    131274-22-1    564483-18-7    890313-93-6 

[1]Patent:EP1820795,2007,A1

496-15-1    890315-75-0    564483-18-7   
tert-butyl2-(benzamido)-4-(indolin-1-yl)benzoate 

[1]Patent:EP1820795,2007,A1

Literature

Title: 3-(2,4-Difluoro-anilino)-9-nitro-dibenzo[b,e]oxepin-11(6H)-one.

Journal: Acta crystallographica. Section E, Structure reports online 20110301

Title: 3-(2,4-Dimeth-oxy-anilino)-8-meth-oxy-dibenz[b,e]oxepin-11(6H)-one.

Journal: Acta crystallographica. Section E, Structure reports online 20110201

Title: Dicyclohexyl(2',4',6'-triisopropylbiphenyl-2-yl)phosphine-dichlorophenylborane.

Journal: Acta crystallographica. Section E, Structure reports online 20091101

Title: Palladium catalysed aryl amination reactions in supercritical carbon dioxide.

Journal: Organic & biomolecular chemistry 20051021

Title: Insights into the origin of high activity and stability of catalysts derived from bulky, electron-rich monophosphinobiaryl ligands in the Pd-catalyzed C-N bond formation.

Journal: Journal of the American Chemical Society 20031119

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Tags:564483-18-7 Molecular Formula|564483-18-7 MDL|564483-18-7 SMILES|564483-18-7 Dicyclohexyl[2-(2,4,6-triisopropylphenyl)phenyl]phosphane