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813-78-5,MFCD00014887
Catalog No.:AA0052N2

813-78-5 | Dimethyl phosphate

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250mg
95%
in stock  
$66.00   $46.00
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1g
95
in stock  
$151.00   $106.00
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5g
95
in stock  
$427.00   $299.00
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  • Technical Information
  • Properties
  • Literature
Technical Information
Catalog Number:
AA0052N2
Chemical Name:
Dimethyl phosphate
CAS Number:
813-78-5
Molecular Formula:
C2H7O4P
Molecular Weight:
126.0483
MDL Number:
MFCD00014887
SMILES:
COP(=O)(OC)O
UN Number:
3265
Properties
Properties
 
BP:
159.8°C at 760 mmHg  
Form:
Liquid  
Refractive Index:
1.408-1.41  
Storage:
Keep in dry area;2-8℃;  

Computed Properties
 
Complexity:
81.7  
Covalently-Bonded Unit Count:
1  
Heavy Atom Count:
7  
Hydrogen Bond Acceptor Count:
4  
Hydrogen Bond Donor Count:
1  
Rotatable Bond Count:
2  
XLogP3:
-1.2  

Literature

Title: Early-life exposure to organophosphate pesticides and pediatric respiratory symptoms in the CHAMACOS cohort.

Journal: Environmental health perspectives 20150201

Title: Dibutyl-ammonium bis-(hydrogen methylphosphonato-κO)triphenylstannate(IV).

Journal: Acta crystallographica. Section E, Structure reports online 20121001

Title: Arsenic in prebiotic species: a theoretical approach.

Journal: Physical chemistry chemical physics : PCCP 20120814

Title: Organophosphate pesticide exposure and perinatal outcomes in Shanghai, China.

Journal: Environment international 20120701

Title: Determining relative rates of cellulose dissolution in ionic liquids through in situ viscosity measurement.

Journal: Chemical communications (Cambridge, England) 20120607

Title: Urinary concentrations of organophosphorus insecticide metabolites in Japanese workers.

Journal: Chemosphere 20120601

Title: Molecularly imprinted polymer sensors for detection in the gas, liquid, and vapor phase.

Journal: Journal of molecular recognition : JMR 20120601

Title: Direct formation of the C5'-radical in the sugar-phosphate backbone of DNA by high-energy radiation.

Journal: The journal of physical chemistry. B 20120524

Title: The atlas of dialkylphosphates; assessment of cumulative human organophosphorus pesticides' exposure.

Journal: Forensic science international 20120510

Title: Have regulatory efforts to reduce organophosphorus insecticide exposures been effective?

Journal: Environmental health perspectives 20120401

Title: Is hair analysis for dialkyl phosphate metabolites a suitable biomarker for assessing past acute exposure to organophosphate pesticides?

Journal: Human & experimental toxicology 20120301

Title: Simultaneous analytical method for urinary metabolites of organophosphorus compounds and moth repellents in general population.

Journal: Journal of chromatography. B, Analytical technologies in the biomedical and life sciences 20120101

Title: Enzyme activity in dialkyl phosphate ionic liquids.

Journal: Bioresource technology 20111201

Title: Metabolomic analysis of the toxic effects of chronic exposure to low-level dichlorvos on rats using ultra-performance liquid chromatography-mass spectrometry.

Journal: Toxicology letters 20111030

Title: Adsorption of trimethyl phosphate on maghemite, hematite, and goethite nanoparticles.

Journal: The journal of physical chemistry. A 20110818

Title: Prenatal exposure to organophosphate pesticides and IQ in 7-year-old children.

Journal: Environmental health perspectives 20110801

Title: Prenatal exposure to organophosphates, paraoxonase 1, and cognitive development in childhood.

Journal: Environmental health perspectives 20110801

Title: Organophosphate pesticide exposure and residential proximity to nearby fields: evidence for the drift pathway.

Journal: Journal of occupational and environmental medicine 20110801

Title: Urinary concentrations of dialkylphosphate metabolites of organophosphorus pesticides: National Health and Nutrition Examination Survey 1999-2004.

Journal: International journal of environmental research and public health 20110801

Title: Assessing diet as a modifiable risk factor for pesticide exposure.

Journal: International journal of environmental research and public health 20110601

Title: Organophosphorus pesticide degradation product in vitro metabolic stability and time-course uptake and elimination in rats following oral and intravenous dosing.

Journal: Xenobiotica; the fate of foreign compounds in biological systems 20110501

Title: Atmospheric chemistry of dichlorvos.

Journal: The journal of physical chemistry. A 20110407

Title: Ion pairing in aqueous electrolyte solutions with biologically relevant anions.

Journal: The journal of physical chemistry. B 20110407

Title: Deconvolution of Raman spectroscopic signals for electrostatic, H-bonding, and inner-sphere interactions between ions and dimethyl phosphate in solution.

Journal: Journal of inorganic biochemistry 20110401

Title: Determinants of organophosphorus pesticide urinary metabolite levels in young children living in an agricultural community.

Journal: International journal of environmental research and public health 20110401

Title: Combined toxic exposures and human health: biomarkers of exposure and effect.

Journal: International journal of environmental research and public health 20110301

Title: Organophosphorous pesticide exposures and sperm quality.

Journal: Reproductive toxicology (Elmsford, N.Y.) 20110101

Title: Pesticide exposure among pregnant women in Jerusalem, Israel: results of a pilot study.

Journal: Environment international 20110101

Title: [A case-control study on correlation of pesticide exposure with childhood acute leukemia].

Journal: Zhonghua yu fang yi xue za zhi [Chinese journal of preventive medicine] 20110101

Title: Association of organophosphate pesticide exposure and paraoxonase with birth outcome in Mexican-American women.

Journal: PloS one 20110101

Title: Organophosphate pesticide exposure and attention in young Mexican-American children: the CHAMACOS study.

Journal: Environmental health perspectives 20101201

Title: The osmolyte TMAO stabilizes native RNA tertiary structures in the absence of Mg2+: evidence for a large barrier to folding from phosphate dehydration.

Journal: Journal of molecular biology 20101119

Title: Quantification of dialkylphosphate metabolites of organophosphorus insecticides in human urine using 96-well plate sample preparation and high-performance liquid chromatography-electrospray ionization-tandem mass spectrometry.

Journal: Journal of chromatography. B, Analytical technologies in the biomedical and life sciences 20101001

Title: Thionate versus Oxon: comparison of stability, uptake, and cell toxicity of ((14)CH(3)O)(2)-labeled methyl parathion and methyl paraoxon with SH-SY5Y cells.

Journal: Journal of agricultural and food chemistry 20100728

Title: Neurobehavioral deficits and increased blood pressure in school-age children prenatally exposed to pesticides.

Journal: Environmental health perspectives 20100601

Title: Sonophotocatalytic degradation of monocrotophos using TiO2 and Fe3+.

Journal: Journal of hazardous materials 20100515

Title: Revised method for routine determination of urinary dialkyl phosphates using gas chromatography-mass spectrometry.

Journal: Journal of chromatography. B, Analytical technologies in the biomedical and life sciences 20100515

Title: Determination of dialkyl phosphates in human hair for the biomonitoring of exposure to organophosphate pesticides.

Journal: Journal of chromatography. B, Analytical technologies in the biomedical and life sciences 20100515

Title: Association between organophosphate pesticides exposure and thyroid hormones in floriculture workers.

Journal: Toxicology and applied pharmacology 20100215

Title: Reaction pathway and free-energy barrier for reactivation of dimethylphosphoryl-inhibited human acetylcholinesterase.

Journal: The journal of physical chemistry. B 20091217

Title: DNA damage in horticultural farmers: a pilot study showing an association with organophosphate pesticide exposure.

Journal: Biomarkers : biochemical indicators of exposure, response, and susceptibility to chemicals 20091101

Title: Assessment of long-term subacute exposure to dimethoate by hair analysis of dialkyl phosphates DMP and DMTP in exposed rabbits: The effects of dose, dose duration and hair colour.

Journal: Environmental research 20091001

Title: Geometrical and vibrational features of phosphate, phosphorothioate and phosphorodithioate linkages interacting with hydrated cations: a DFT study.

Journal: Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy 20090901

Title: Combined suicide by oxydemeton-methyl (Metasystox) ingestion and hanging.

Journal: Forensic science international 20090810

Title: Ionic liquids as superior solvents for headspace gas chromatography of residual solvents with very low vapor pressure, relevant for pharmaceutical final dosage forms.

Journal: Journal of chromatography. A 20090807

Title: Kinetics and mechanism for degradation of dichlorvos by permanganate in drinking water treatment.

Journal: Water research 20090801

Title: Variation across the agricultural season in organophosphorus pesticide urinary metabolite levels for Latino farmworkers in eastern North Carolina: project design and descriptive results.

Journal: American journal of industrial medicine 20090701

Title: A mass spectrometry-based method to measure dialkylphosphate degradation products of organophosphorous insecticides in dust and orange juice.

Journal: Journal of environmental monitoring : JEM 20090701

Title: Dimethyl [(4-fluoro-phen-yl)(6-methoxy-benzothia-zol-2-ylamino)meth-yl]phospho-nate.

Journal: Acta crystallographica. Section E, Structure reports online 20090601

Title: Dialkyl phosphates in meconium as a biomarker of prenatal exposure to organophosphate pesticides: a study on pregnant women of rural areas in Crete, Greece.

Journal: Xenobiotica; the fate of foreign compounds in biological systems 20090501

Title: Analysis of dialkyl phosphate metabolites in hair using gas chromatography-mass spectrometry: a biomarker of chronic exposure to organophosphate pesticides.

Journal: Biomarkers : biochemical indicators of exposure, response, and susceptibility to chemicals 20090501

Title: Molecular dynamics simulations of a DMPC bilayer using nonadditive interaction models.

Journal: Biophysical journal 20090121

Title: Determination of dialkyl phosphates as breakdown products of organophosphorus insecticides in fruit juices by HPTLC with fluorescence detection.

Journal: Journal of AOAC International 20090101

Title: Hydrolytic cleavage of an RNA-model phosphodiester catalyzed by a highly negatively charged polyoxomolybdate [Mo7O24]6- cluster.

Journal: Journal of the American Chemical Society 20081224

Title: Theoretical investigation of the reaction mechanism for the phosphate diester hydrolysis using an asymmetric dinuclear metal complex as a biomimetic model of the purple acid phosphatase enzyme.

Journal: Physical chemistry chemical physics : PCCP 20081214

Title: Dialkylphosphates (DAPs) in fruits and vegetables may confound biomonitoring in organophosphorus insecticide exposure and risk assessment.

Journal: Journal of agricultural and food chemistry 20081126

Title: Polyionic charge density plays a key role in differential recognition of mobile ions by biopolymers.

Journal: The journal of physical chemistry. B 20080731

Title: A fatal dichlorvos poisoning: concentrations in biological specimens.

Journal: Journal of forensic sciences 20080701

Title: Control of molecular fragmentation using shaped femtosecond pulses.

Journal: The journal of physical chemistry. A 20080501

Title: Para niños saludables: a community intervention trial to reduce organophosphate pesticide exposure in children of farmworkers.

Journal: Environmental health perspectives 20080501

Title: Ca2+-dimethylphosphate complex formation: providing insight into Ca2+-mediated local dehydration and membrane fusion in cells.

Journal: Cell biology international 20080401

Title: 31P chemical shift tensors for canonical and non-canonical conformations of nucleic acids: a DFT study and NMR implications.

Journal: The journal of physical chemistry. B 20080320

Title: A rapid, cost-effective method for analyzing organophosphorus pesticide metabolites in human urine for counter-terrorism response.

Journal: Journal of analytical toxicology 20080101

Title: Potential developmental neurotoxicity of pesticides used in Europe.

Journal: Environmental health : a global access science source 20080101

Title: Semen quality in Peruvian pesticide applicators: association between urinary organophosphate metabolites and semen parameters.

Journal: Environmental health : a global access science source 20080101

Title: Understanding membrane fusion combining experimental and simulation studies.

Journal: Methods in cell biology 20080101

Title: A Staphylococcus aureus ypfP mutant with strongly reduced lipoteichoic acid (LTA) content: LTA governs bacterial surface properties and autolysin activity.

Journal: Molecular microbiology 20070801

Title: Prenatal organophosphate metabolite and organochlorine levels and performance on the Brazelton Neonatal Behavioral Assessment Scale in a multiethnic pregnancy cohort.

Journal: American journal of epidemiology 20070615

Title: Organophosphate pesticide exposure and neurodevelopment in young Mexican-American children.

Journal: Environmental health perspectives 20070501

Title: Relationships between 31P chemical shift tensors and conformation of nucleic acid backbone: a DFT study.

Journal: The journal of physical chemistry. B 20070315

Title: 8-Hydroxydeoxyguanosine levels in human leukocyte and urine according to exposure to organophosphorus pesticides and paraoxonase 1 genotype.

Journal: International archives of occupational and environmental health 20070101

Title: [Electronic and spacial structure of orthophosphate and dimethylorthophosphate].

Journal: Biofizika 20070101

Title: Potential uses of biomonitoring data: a case study using the organophosphorus pesticides chlorpyrifos and malathion.

Journal: Environmental health perspectives 20061101

Title: Transition state analogues for nucleotidyl transfer reactions: Structure and stability of pentavalent vanadate and phosphate ester dianions.

Journal: The journal of physical chemistry. B 20060803

Title: Organophosphate pesticide exposure and work in pome fruit: evidence for the take-home pesticide pathway.

Journal: Environmental health perspectives 20060701

Title: Organophosphate pesticide exposure and neurobehavioral performance in agricultural and non-agricultural Hispanic workers.

Journal: Environmental health perspectives 20060501

Title: Association of in utero organochlorine pesticide exposure and fetal growth and length of gestation in an agricultural population.

Journal: Environmental health perspectives 20060401

Title: Simultaneous determination of urinary dialkylphosphate metabolites of organophosphorus pesticides using gas chromatography-mass spectrometry.

Journal: Journal of chromatography. B, Analytical technologies in the biomedical and life sciences 20060217

Title: Simultaneous determination of six dialkylphosphates in urine by liquid chromatography tandem mass spectrometry.

Journal: Journal of chromatography. B, Analytical technologies in the biomedical and life sciences 20060202

Title: A case for revisiting the safety of pesticides: a closer look at neurodevelopment.

Journal: Environmental health perspectives 20060101

Title: [Study on decomposed products of trichlorfon in process of gas chromatographic analysis by mass spectrometry].

Journal: Se pu = Chinese journal of chromatography 20060101

Title: Dialkyl phosphate metabolites of organophosphorus in applicators of agricultural pesticides in Majes - Arequipa (Peru).

Journal: Journal of occupational medicine and toxicology (London, England) 20060101

Title: Organophosphate urinary metabolite levels during pregnancy and after delivery in women living in an agricultural community.

Journal: Environmental health perspectives 20051201

Title: Theoretical studies of the hydroxide-catalyzed P-O cleavage reactions of neutral phosphate triesters and diesters in aqueous solution: examination of the changes induced by H/Me substitution.

Journal: The journal of physical chemistry. B 20051201

Title: Catalytic transesterification of dialkyl phosphates by a bioinspired dicopper(II) macrocyclic complex.

Journal: Journal of the American Chemical Society 20051102

Title: Does phosphoryl protonation occurs in aqueous phosphoesters solutions.

Journal: Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy 20051101

Title: Biologic monitoring to characterize organophosphorus pesticide exposure among children and workers: an analysis of recent studies in Washington State.

Journal: Environmental health perspectives 20051101

Title: Lessons learned for the assessment of children's pesticide exposure: critical sampling and analytical issues for future studies.

Journal: Environmental health perspectives 20051001

Title: A comprehensive evaluation of the testicular toxicity of dichlorvos in Wistar rats.

Journal: Toxicology 20050915

Title: Pesticide exposure alters follicle-stimulating hormone levels in Mexican agricultural workers.

Journal: Environmental health perspectives 20050901

Title: Methyl-parathion and organophosphorous pesticide metabolites modify the activation status and interleukin-2 secretion of human peripheral blood mononuclear cells.

Journal: Toxicology letters 20050728

Title: Effect of Zn...Zn separation on the hydrolytic activity of model dizinc phosphodiesterases.

Journal: Chemistry (Weinheim an der Bergstrasse, Germany) 20050718

Title: Thiolysis and alcoholysis of phosphate tri- and monoesters with alkyl and aryl leaving groups. An ab initio study in the gas phase.

Journal: The journal of physical chemistry. A 20050630

Title: Increased expression of a bacterial phosphotriesterase in Escherichia coli through directed evolution.

Journal: Protein expression and purification 20050601

Title: Assessing exposure to organophosphorus pesticides by biomonitoring in epidemiologic studies of birth outcomes.

Journal: Environmental health perspectives 20050401

Title: Variation in organophosphate pesticide metabolites in urine of children living in agricultural communities.

Journal: Environmental health perspectives 20050401

Title: Metal-cation-mediated hydrolysis of phosphonoformate diesters: chemoselectivity and catalysis(1).

Journal: Journal of the American Chemical Society 20040908

Title: An estimation of the exposure to organophosphorus pesticides through the simultaneous determination of their main metabolites in urine by liquid chromatography-tandem mass spectrometry.

Journal: Journal of chromatography. B, Analytical technologies in the biomedical and life sciences 20040905

Title: Association of in utero organophosphate pesticide exposure and fetal growth and length of gestation in an agricultural population.

Journal: Environmental health perspectives 20040701

Title: Theoretical method for full ab initio calculation of DNA/RNA-ligand interaction energy.

Journal: The Journal of chemical physics 20040622

Title: Hydrolysis of organophosphorus insecticides by in vitro modified carboxylesterase E3 from Lucilia cuprina.

Journal: Insect biochemistry and molecular biology 20040401

Title: Acute poisoning with phosphamidon: determination of dimethyl phosphate (DMP) as a stable metabolite in a case of organophosphate insecticide intoxication.

Journal: Journal of analytical toxicology 20040401

Title: Biodegradation and bioaccumulation of fenitrothion in rat liver.

Journal: Biomedical chromatography : BMC 20040301

Title: Concentrations of dialkyl phosphate metabolites of organophosphorus pesticides in the U.S. population.

Journal: Environmental health perspectives 20040201

Title: Rapid and sensitive quantitative analysis of alkyl phosphates in urine after organophosphate poisoning.

Journal: Journal of analytical toxicology 20040101

Title: Measurement of pesticides and other toxicants in amniotic fluid as a potential biomarker of prenatal exposure: a validation study.

Journal: Environmental health perspectives 20031101

Title: Chemical force microscopy investigation of phosphate adsorption on the surfaces of iron(III) oxyhydroxide particles.

Journal: Journal of colloid and interface science 20021015

Title: Synergistic effect between metal coordination and hydrogen bonding in phosphate and halide recognition.

Journal: Journal of the American Chemical Society 20020918

Title: Theoretical evaluation of pK(a) in phosphoranes: implications for phosphate ester hydrolysis.

Journal: Journal of the American Chemical Society 20020508

Title: Solvent effects on the reaction coordinate of the hydrolysis of phosphates and sulfates: application of Hammond and anti-Hammond postulates to understand hydrolysis in solution.

Journal: Journal of the American Chemical Society 20011128

Title: The magnitude of [C-H...O] hydrogen bonding in molecular and supramolecular assemblies.

Journal: Journal of the American Chemical Society 20010926

Title: A bioinspired dicopper(II) catalyst for the transesterification of dimethyl phosphate.

Journal: Journal of the American Chemical Society 20010822

Title: Negative ion chemical ionization GC/MS-MS analysis of dialkylphosphate metabolites of organophosphate pesticides in urine of non-occupationally exposed subjects.

Journal: The Analyst 20010701

Title: Measurement of organophosphate metabolites in postpartum meconium as a potential biomarker of prenatal exposure: a validation study.

Journal: Environmental health perspectives 20010401

Title: Ultrasonic irradiation of dichlorvos: decomposition mechanism.

Journal: Water research 20010301

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Tags:813-78-5 Molecular Formula|813-78-5 MDL|813-78-5 SMILES|813-78-5 Dimethyl phosphate